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Does Mastering a Skill give Talent experience?
Maybe it's not specifically mastery, but filling out the training requirements.
I have fledgling Construct Alchemy with 2/3 of the talent exp bar filled and fledgling Battle Alchemy with about 3/10 of the bar filled, even though all the alchemy skills I have are ranked novice. I've finished the requirements for rank novice Synthesis, Mana Crystallization, Alchemy Mastery, Water Cannon and wind blast and half the requirement for Summon Golem. The rest of my alchemy skills haven't been started and I haven't even acquired Transmutation, Heat Buster, Frozen Blast, Flame Burst, Chain Cylinder, Sand Burst, or the alchemy element masteries.
Unless you get talent experience just for discovering a skill, you get a small amount for finishing the level up requirements.